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  Synthesis and Characterization of Bis[bis(pentafluoroethyl)phosphinyl]imides, M+N[(C2F5)2P(O)]2−, M = H, Na, K, Cs, Ag, Me4N

Bejan, D., Willner, H., Ignatiev, N., & Lehmann, C. W. (2008). Synthesis and Characterization of Bis[bis(pentafluoroethyl)phosphinyl]imides, M+N[(C2F5)2P(O)]2−, M = H, Na, K, Cs, Ag, Me4N. Inorganic Chemistry, 47(19), 9085-9089. doi:10.1021/ic801088q.

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Bejan, Dana1, Author
Willner, Helge1, Author
Ignatiev, Nikolai2, Author
Lehmann, Christian W.3, Author              
Affiliations:
1Bergische Universität Wuppertal, FB C — Anorganische Chemie, Gauss Strasse 20, D-42097 Wuppertal, Germany, ou_persistent22              
2Merck KGaA Company, Frankfurter Strasse 250, D-64293 Darmstadt, Germany, ou_persistent22              
3Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: A convenient synthesis and a full characterization of the strong acid bis[bis(pentafluoroethyl)phosphinyl]imide and some of its salts M+N[(C2F5)2P(O)]2−, M = Na, K, Cs, Ag, Me4N, are presented. Their thermal (mp, Tdec.) and spectroscopic (IR, Raman, NMR) properties are discussed. A single crystal structure of [Me4N][N{P(O)(C2F5)2}2] has been obtained, and the structural parameters of the anion are compared with the results of quantum-chemical calculations. The observed properties are comparable to those of bis((trifluoromethyl)sulfonyl)imide and their derivatives.

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Language(s): eng - English
 Dates: 2008-06-122008-08-202008-10-06
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ic801088q
 Degree: -

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Title: Inorganic Chemistry
  Abbreviation : Inorg. Chem.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 47 (19) Sequence Number: - Start / End Page: 9085 - 9089 Identifier: ISSN: 0020-1669
CoNE: https://pure.mpg.de/cone/journals/resource/0020-1669