非表示:
キーワード:
Hydrogen storage; Complex aluminium deuterides; Mechanochemical synthesis; Ball milling
要旨:
We describe the ball-milling synthesis of alkali metal deuterides from commercial lithium aluminium deuteride. This reaction principle was exemplified by the mechanochemical synthesis of NaAlD4 and KAlD4. NaAlD4 was prepared on the multi-gram scale by this procedure and purified by standard wet-chemical separation. Pure NaAlD4 was obtained and used for the synthesis of Ca(AlD4)2. The formation of all products was verified by X-ray diffraction.
