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  Dynamics of Silicate Species in Solution Studied by Mass Spectrometry with Isotopically Labeled Compounds

Pelster, S. A., Weimann, B., Schaack, B. B., Schrader, W., & Schüth, F. (2007). Dynamics of Silicate Species in Solution Studied by Mass Spectrometry with Isotopically Labeled Compounds. Angewandte Chemie International Edition, 46(35), 6674-6677. doi:10.1002/anie.200701927.

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 Creators:
Pelster, Stefan Alexander1, Author              
Weimann, Bruno2, Author              
Schaack, Bernd Bastian3, Author              
Schrader, Wolfgang1, Author              
Schüth, Ferdi3, Author              
Affiliations:
1Service Department Schrader (MS), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445629              
2Service Department Ziegler (IT), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445633              
3Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              

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Free keywords: hydrothermal synthesis; isotopic labeling; kinetics; mass spectrometry; silicates
 Abstract: Concerted exchange of four and three Si atoms is respectively responsible for interconversion of cubic octameric (picture: quality of a fit for single‐ (A), two‐ (B), and four‐atom exchange (C); C fits the experimental pattern best) and prismatic hexameric silicate species in solution according to mass spectrometry with isotopically labeled compounds. These findings have important implications for nucleation and growth processes of zeolites and other silicates.

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Language(s): eng - English
 Dates: 2007-05-022007-08-272007-09-03
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200701927
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 46 (35) Sequence Number: - Start / End Page: 6674 - 6677 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851