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  (PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3:  Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphine)rhodium(I)

Finze, M., Bernhardt, E., Willner, H., & Lehmann, C. W. (2006). (PPh3)3RhCNB(CF3)3 and (PPh3)3RhNCB(CF3)3:  Isocyano- and Cyanoborate Complexes of Tris(triphenylphosphine)rhodium(I). Organometallics, 25(12), 3070-3075. doi:10.1021/om060135z.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-944F-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-1BD3-D
Genre: Journal Article

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 Creators:
Finze, Maik1, Author
Bernhardt, Eduard1, Author
Willner, Helge1, Author
Lehmann, Christian W.2, Author           
Affiliations:
1FB C-Anorganische Chemie, Bergische Universität Wuppertal, Gaussstrasse 20, D-42097 Wuppertal, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: The reactions of K[(CF3)3BNC] and K[(CF3)3BCN] with (PPh3)3RhCl in ethanol resulted in the rhodium(I) complexes (PPh3)3RhNCB(CF3)3 and (PPh3)3RhCNB(CF3)3, respectively. Their 15N-labeled isotopomers were synthesized from the corresponding borate anions. The complexes were characterized by UV, Raman, and multi-NMR spectroscopy, and the crystal structures were obtained. The spectroscopic and structural data are compared to those of the potassium borates and to related rhodium(I) complexes.

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Language(s): eng - English
 Dates: 2006-02-132006-04-282006-06-01
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/om060135z
 Degree: -

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Title: Organometallics
  Other : Organometallics
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 25 (12) Sequence Number: - Start / End Page: 3070 - 3075 Identifier: ISSN: 0276-7333
CoNE: https://pure.mpg.de/cone/journals/resource/954925505259