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  Imidazo[1,5-a]pyridine-3-ylidenes - pyridine derived N-heterocyclic carbene ligands

Burstein, C., Lehmann, C. W., & Glorius, F. (2005). Imidazo[1,5-a]pyridine-3-ylidenes - pyridine derived N-heterocyclic carbene ligands. Tetrahedron, 61(26), 6207-6217. doi:10.1016/j.tet.2005.03.115.

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 Creators:
Burstein, Christian1, Author              
Lehmann, Christian W.2, Author              
Glorius, Frank1, Author              
Affiliations:
1Research Group Glorius, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445602              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: Ligand design; N-heterocyclic carbene; Suzuki-Miyaura cross-coupling
 Abstract: The ready synthesis of differently substituted 2H-imidazo[1,5-a]pyridin-4-ium bromides is reported. These salts are precursors for a new class of N-heterocyclic carbene ligands. As a consequence of their bicyclic geometry, these ligands are capable of influencing the coordination sphere of a carbene bound metal. The usefulness of these ligands was demonstrated in the palladium-catalyzed Suzuki–Miyaura cross-coupling of sterically hindered aryl chlorides.

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Language(s): eng - English
 Dates: 2004-12-042005-05-232005-06-27
 Publication Status: Published in print
 Pages: 11
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/j.tet.2005.03.115
 Degree: -

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Title: Tetrahedron
  Other : Tetrahedron
Source Genre: Journal
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Affiliations:
Publ. Info: Kidlington : Elsevier Science
Pages: - Volume / Issue: 61 (26) Sequence Number: - Start / End Page: 6207 - 6217 Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/00404020