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  Cross-Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low-Valent Iron Complex

Martin, R., & Fürstner, A. (2004). Cross-Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a Low-Valent Iron Complex. Angewandte Chemie, International Edition, 43(30), 3955-3957. doi:10.1002/anie.200460504.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-96DF-0 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0028-13E9-7
Genre: Journal Article

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 Creators:
Martin, Rubén1, Author           
Fürstner, Alois1, Author           
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: alkyl halides; cross-coupling; Grignard reagents; iron
 Abstract: A striking reversal of the usual reactivity pattern of aryl Grignard reagents is observed for reactions in the presence of catalytic amounts of the “bare” ferrate complex [Li(tmeda)]2[Fe(C2H4)4] (1). Highly reduced iron–magnesium clusters may play a decisive role in the exceptionally facile and chemoselective cross-coupling reaction with alkyl halides.

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Language(s): eng - English
 Dates: 2004-04-292004-07-072004-07-26
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 218358
DOI: 10.1002/anie.200460504
ISI: 000223047200017
 Degree: -

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Title: Angewandte Chemie, International Edition
  Other : Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 43 (30) Sequence Number: - Start / End Page: 3955 - 3957 Identifier: Other: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851