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  51-(3,6-tBu2Flu)SiMe2NtBu]Y(η1 -NC5H6)(py)2: A 1,4-Hydride-Addition Product to Pyridine that Provides Evidence for the First Fluorenyl(hydrido)metal (Group 3) Complex

Kirillov, E., Lehmann, C. W., Razavi, A., & Carpentier, J.-F. (2004).51-(3,6-tBu2Flu)SiMe2NtBu]Y(η1 -NC5H6)(py)2: A 1,4-Hydride-Addition Product to Pyridine that Provides Evidence for the First Fluorenyl(hydrido)metal (Group 3) Complex. European Journal of Inorganic Chemistry, 2004(5), 943-945. doi:10.1002/ejic.200300837.

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 Creators:
Kirillov, Evgueni1, Author
Lehmann, Christian W.2, Author           
Razavi, Abbas3, Author
Carpentier, Jean-François1, Author
Affiliations:
1Organométalliques et Catalyse, UMR 6509 CNRS‐Université de Rennes 1, Institut de Chimie de Rennes, 35042 Rennes Cedex, France, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
3Atofina Research, Zone Industrielle C, 7181 Feluy, Belgium, ou_persistent22              

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Free keywords: Fluorenyl; Hydrides; Insertion; Pyridine; Yttrium
 Abstract: Reaction of pyridine with the “constrained geometry” fluorenyl(hydrido)yttrium complex {[(3,6‐tBu2Flu)SiMe2NtBu]Y(H)(THF)}2 selectively gives the 1,4‐addition product [η51‐(3,6‐tBu2Flu)SiMe2NtBu]Y(η1‐NC5H6)(py)2, which was characterized by single‐crystal X‐ray diffraction and 1H and 13C NMR spectroscopy.

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Language(s): eng - English
 Dates: 2004-03-01
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ejic.200300837
 Degree: -

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Title: European Journal of Inorganic Chemistry
  Abbreviation : Eur. J. Inorg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: 2004 (5) Sequence Number: - Start / End Page: 943 - 945 Identifier: ISSN: 1434-1948
CoNE: https://pure.mpg.de/cone/journals/resource/954926953810_1