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  Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis

Altenhoff, G., Goddard, R., Lehmann, C. W., & Glorius, F. (2004). Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with Restricted Flexibility for Catalysis. Journal of the American Chemical Society, 126(46), 15195-15201. doi:10.1021/ja045349r.

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 Creators:
Altenhoff, Gereon1, Author              
Goddard, Richard2, Author              
Lehmann, Christian W.2, Author              
Glorius, Frank1, Author              
Affiliations:
1Research Group Glorius, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445602              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: A unique family of N-heterocyclic carbenes derived from bioxazolines (IBiox) suitable for application in transition-metal catalysis is described. The ligands are electron rich, sterically demanding, and have restricted flexibility. Their usefulness has been demonstrated in the Suzuki−Miyaura cross-coupling of sterically hindered aryl chlorides and boronic acids. For the first time, tetraortho-substituted biaryls with methyl and larger ortho-substituents have been synthesized from aryl chlorides using the Suzuki−Miyaura method.

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Language(s): eng - English
 Dates: 2004-08-022004-10-282004-11-01
 Publication Status: Published in print
 Pages: 7
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja045349r
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 126 (46) Sequence Number: - Start / End Page: 15195 - 15201 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870