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  Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide Complexes

Kirillov, E., Lehmann, C. W., Razavi, A., & Carpentier, J.-F. (2004). Highly Syndiospecific Polymerization of Styrene Catalyzed by Allyl Lanthanide Complexes. Journal of the American Chemical Society, 126(39), 12240-12241. doi:10.1021/ja0455695.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-976B-E Version Permalink: https://hdl.handle.net/21.11116/0000-0007-16FB-6
Genre: Journal Article

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 Creators:
Kirillov, Evgueni1, Author
Lehmann, Christian W.2, Author           
Razavi, Abbas3, Author
Carpentier, Jean-François1, Author
Affiliations:
1Organométalliques et Catalyse, UMR 6509 CNRS-Université de Rennes 1, Institut de Chimie de Rennes, 35042 Rennes Cedex, France, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
3Atofina Research, Zone Industrielle C, 7181 Feluy, Belgium , ou_persistent22              

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 Abstract: Allylic complexes of lanthanides bearing a fluorenyl-based ligand are active single-component catalysts for the polymerization of styrene, giving highly syndiotactic polymers (rrrr > 99%) with low to high molecular weight (Mn = 8000−135 000) and narrow polydispersities (Mw/Mn = 1.25−2.1).

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Language(s): eng - English
 Dates: 2004-07-232004-10-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja0455695
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 126 (39) Sequence Number: - Start / End Page: 12240 - 12241 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870