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  Preparation of Metal-Imidazolidin-2-ylidene Complexes by Oxidative Addition

Fürstner, A., Seidel, G., Kremzow, D., & Lehmann, C. W. (2003). Preparation of Metal-Imidazolidin-2-ylidene Complexes by Oxidative Addition. Organometallics, 22(5), 907-909. doi:10.1021/om021022s.

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[164]SI.pdf (Supplementary material), 889KB
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 Creators:
Fürstner, Alois1, Author              
Seidel, Günter1, Author              
Kremzow, Doris1, Author              
Lehmann, Christian W.2, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: An entry into (chiral) palladium complexes bearing N-heterocyclic carbene (NHC) ligands is outlined on the basis of the oxidative addition of Pd(PPh3)4 to easily accessible (enantiopure) 2-chloro-1,3-disubstituted imidazolinium salts. This procedure is complementary to existing methodology that relies on metathetic ligand exchange reactions without changing the oxidation state of the involved metal center.

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Language(s): eng - English
 Dates: 2002-12-182003-01-312003-03-03
 Publication Status: Published in print
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 119185
DOI: 10.1021/om021022s
ISI: 000181208100005
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Title: Organometallics
  Other : Organometallics
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 22 (5) Sequence Number: - Start / End Page: 907 - 909 Identifier: ISSN: 0276-7333
CoNE: https://pure.mpg.de/cone/journals/resource/954925505259