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  An N‐Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross‐Coupling of Sterically Hindered Aryl Chlorides at Room Temperature

Altenhoff, G., Goddard, R., Lehmann, C. W., & Glorius, F. (2003). An N‐Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross‐Coupling of Sterically Hindered Aryl Chlorides at Room Temperature. Angewandte Chemie International Edition, 42(31), 3690-3693. doi:10.1002/anie.200351325.

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 Creators:
Altenhoff, Gereon1, Author              
Goddard, Richard2, Author              
Lehmann, Christian W.2, Author              
Glorius, Frank1, Author              
Affiliations:
1Research Group Glorius, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445602              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: biaryls; carbene ligands; C-C coupling; cross-coupling; palladium
 Abstract: A juggling act: The steric bulk of the ligand enhances reductive elimination in the Pd‐catalyzed Suzuki cross‐coupling. However, it impedes the oxidative addition and transmetallation of sterically hindered substrates. This dilemma is solved with the carbene ligand 1, which exhibits flexible steric bulk.

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Language(s): eng - English
 Dates: 2003-08-11
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200351325
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 42 (31) Sequence Number: - Start / End Page: 3690 - 3693 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851