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  An N‐Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross‐Coupling of Sterically Hindered Aryl Chlorides at Room Temperature

Altenhoff, G., Goddard, R., Lehmann, C. W., & Glorius, F. (2003). An N‐Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross‐Coupling of Sterically Hindered Aryl Chlorides at Room Temperature. Angewandte Chemie International Edition, 42(31), 3690-3693. doi:10.1002/anie.200351325.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-98DF-2 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-154B-E
Genre: Journal Article

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 Creators:
Altenhoff, Gereon1, Author           
Goddard, Richard2, Author           
Lehmann, Christian W.2, Author           
Glorius, Frank1, Author           
Affiliations:
1Research Group Glorius, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445602              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: biaryls; carbene ligands; C-C coupling; cross-coupling; palladium
 Abstract: A juggling act: The steric bulk of the ligand enhances reductive elimination in the Pd‐catalyzed Suzuki cross‐coupling. However, it impedes the oxidative addition and transmetallation of sterically hindered substrates. This dilemma is solved with the carbene ligand 1, which exhibits flexible steric bulk.

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Language(s): eng - English
 Dates: 2003-08-11
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200351325
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 42 (31) Sequence Number: - Start / End Page: 3690 - 3693 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851