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  On the state of the titanium and zirconium in Ti- or Zr-doped NaAlH4 hydrogen storage material

Weidenthaler, C., Pommerin, A., Felderhoff, M., Bogdanović, B., & Schüth, F. (2003). On the state of the titanium and zirconium in Ti- or Zr-doped NaAlH4 hydrogen storage material. Physical Chemistry Chemical Physics, 5(22), 5149-5153. doi:10.1039/b309409j.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-98F9-6 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-51EF-1
Genre: Journal Article

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 Creators:
Weidenthaler, Claudia1, Author           
Pommerin, André1, Author           
Felderhoff, Michael1, Author           
Bogdanović, Borislav2, Author
Schüth, Ferdi1, Author           
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
2Research Group Bogdanović, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_persistent22              

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 Abstract: The state of the titanium and zirconium in metal doped NaAlH4 was studied by X-ray diffraction analysis and quantitative Rietveld refinements. For the Ti-doped system, Ti is present in a highly dispersed, X-ray amorphous phase together with metallic aluminium. After the extraction of NaAlH4, an Al–Ti alloy forms upon heating of the solid. For the Zr-doped system, an Al–Zr alloy forms already during the doping procedure and remains during the de- and rehydrogenation cycles.

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Language(s): eng - English
 Dates: 2003-08-062003-09-292003-10-142003-11-14
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/b309409j
 Degree: -

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Title: Physical Chemistry Chemical Physics
  Abbreviation : Phys. Chem. Chem. Phys.
Source Genre: Journal
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Publ. Info: Cambridge, England : Royal Society of Chemistry
Pages: - Volume / Issue: 5 (22) Sequence Number: - Start / End Page: 5149 - 5153 Identifier: ISSN: 1463-9076
CoNE: https://pure.mpg.de/cone/journals/resource/954925272413_1