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  The fluoroacyltris(trifluoromethyl)borate ion, [(CF3)3BC(O)F]-, a fluoroacylboron complex

Finze, M., Bernhardt, E., Willner, H., & Lehmann, C. W. (2003). The fluoroacyltris(trifluoromethyl)borate ion, [(CF3)3BC(O)F]-, a fluoroacylboron complex. Angewandte Chemie International Edition, 42(9), 1052-1055. doi:10.1002/anie.200390272.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-990B-5 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-154D-C
Genre: Journal Article

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 Creators:
Finze, Maik1, Author
Bernhardt, Eduard1, Author
Willner, Helge1, Author
Lehmann, Christian W.2, Author           
Affiliations:
1Fakultät 4, Anorganische Chemie, Gerhard‐Mercator‐Universität Duisburg, Lotharstrasse 1, 47048 Duisburg, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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Free keywords: borates; density functional calculations; fluoroacyl ligands; NMR spectroscopy; vibrational spectroscopy
 Abstract: Nucleophilic addition of fluoride ions at the carbonyl carbon atom in (CF3)3BCO in liquid sulfur dioxide leads to the formation of the boron acyl fluoride ion [(CF3)3BC(O)F]− (see structural formula), the first example of a compound with a BC(O)F group and an anionic acyl fluoride.

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Language(s): eng - English
 Dates: 2003-03-03
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200390272
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 42 (9) Sequence Number: - Start / End Page: 1052 - 1055 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851