ausblenden:
Schlagwörter:
borates; density functional calculations; fluoroacyl ligands; NMR spectroscopy; vibrational spectroscopy
Zusammenfassung:
Nucleophilic addition of fluoride ions at the carbonyl carbon atom in (CF3)3BCO in liquid sulfur dioxide leads to the formation of the boron acyl fluoride ion [(CF3)3BC(O)F]− (see structural formula), the first example of a compound with a BC(O)F group and an anionic acyl fluoride.
