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  [Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal‐Bipyramidal Metal–Carbonyl Cation

Bernhardt, E., Finze, M., Willner, H., Lehmann, C. W., & Aubke, F. (2003). [Co(CO)5][(CF3)3BF]: A Stable Salt of a Homoleptic Trigonal‐Bipyramidal Metal–Carbonyl Cation. Angewandte Chemie International Edition, 42(18), 2077-2079. doi:10.1002/anie.200250780.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000F-9911-6 Version Permalink: https://hdl.handle.net/21.11116/0000-0007-154A-F
Genre: Journal Article

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 Creators:
Bernhardt, Eduard1, Author
Finze, Maik1, Author
Willner, Helge1, Author
Lehmann, Christian W.2, Author           
Aubke, Friedhelm3, Author
Affiliations:
1Fakultät 4, Anorganische Chemie, Universität Duisberg‐Essen, Lotharstrasse 1, 47048 Duisburg, Germany, ou_persistent22              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              
3Department of Chemistry, The University of British Columbia, Vancouver B.C. V6T1Z1, Canada, ou_persistent22              

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Free keywords: borates; carbonyl ligands; cobalt complexes; structure elucidation; superacids
 Abstract: Cobalt takes to superacid: By using the superacid system (CF3)3BCO and anhydrous HF the title complex (see structure O blue, C black, Co cyan, F red, B light brown) is formed in a one pot reaction of [Co2(CO)8]. The oxidizing agent is postulated to be H2F+solv. which is generated in situ.

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Language(s): eng - English
 Dates: 2003-05-09
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200250780
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 42 (18) Sequence Number: - Start / End Page: 2077 - 2079 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851