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  Silver-catalyzed oxidation of ethylene to ethylene oxide in a microreaction system

Kestenbaum, H., Lange de Oliveira, A., Schmidt, W., Schüth, F., Ehrfeld, W., Gebauer, K., et al. (2002). Silver-catalyzed oxidation of ethylene to ethylene oxide in a microreaction system. Industrial & Engineering Chemistry Research, 41(4), 710-719. doi:10.1021/ie010306u.

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Kestenbaum, H.1, Autor           
Lange de Oliveira, A.1, Autor           
Schmidt, W.2, Autor           
Schüth, F.1, Autor           
Ehrfeld, W.3, Autor
Gebauer, K.3, Autor
Löwe, H.3, Autor
Richter, T.3, Autor
Lebiedz, D.3, Autor
Untiedt, I.3, Autor
Züchner, H.3, Autor
Affiliations:
1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              
2Research Group Schmidt, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445618              
3Inst Mikrotech Mainz IMM GMBH, D-55129 Mainz, Germany; Univ Münster, D-48149 Münster, Germany, ou_persistent22              

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 Zusammenfassung: Ethylene oxide synthesis has been chosen as a benchmark case to evaluate the performance of a microreaction system in comparison to an existing industrial process. This reaction was selected because microreaction technology provides equipment with very good mass- and heat-transfer conditions, which avoids hot spots inside the reactor channels that are known problems for the partial oxidation of ethylene. Furthermore, because the microstructured reactors are inherently safe with respect to explosions, gas compositions within the explosion limits are attainable and can be handled safely. For example, 15% ethylene in pure oxygen, which is in the middle of the explosive regime and far away from typical compositions for industrial processes, could be used. Space time yields of 0.14-0.78 tons h(-1) m(-1) calculated on the basis of the channel volume, in comparison to the values of 0.13-0.26 tons h(-1) m(-3) for an industrial reactor calculated on the basis of the reactor volume, have been achieved by using the microreactor.

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Sprache(n): eng - English
 Datum: 2002-02-20
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: eDoc: 20162
DOI: 10.1021/ie010306u
ISI: 000173965700008
 Art des Abschluß: -

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Titel: Industrial & Engineering Chemistry Research
  Alternativer Titel : Ind. Eng. Chem. Res.
Genre der Quelle: Zeitschrift
 Urheber:
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Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 41 (4) Artikelnummer: - Start- / Endseite: 710 - 719 Identifikator: ISSN: 0888-5885