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  Study Concerning the Effects of Chelation on the Structure and Catalytic Activity of Ruthenium Carbene Complexes

Fürstner, A., Thiel, O. R., & Lehmann, C. W. (2002). Study Concerning the Effects of Chelation on the Structure and Catalytic Activity of Ruthenium Carbene Complexes. Organometallics, 21(2), 331-335. doi:10.1021/om0108503.

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 Creators:
Fürstner, Alois1, Author              
Thiel, Oliver R.1, Author              
Lehmann, Christian W.2, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445625              

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 Abstract: The ruthenium chelate complexes 4 and 5 were prepared by reaction of the Grubbs catalyst 1 and its second-generation analogue 2 with the 2-vinylbenzoic acid isopropyl ester 3 in the presence of CuCl. The fact that the chelating carbonyl group in these complexes attenuates their catalytic activity sets an experimental basis for the interpretation of reactivity data previously described in the literature.

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Language(s): eng - English
 Dates: 2001-09-262001-12-182002-01-01
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/om0108503
 Degree: -

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Title: Organometallics
  Other : Organometallics
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: - Volume / Issue: 21 (2) Sequence Number: - Start / End Page: 331 - 335 Identifier: ISSN: 0276-7333
CoNE: https://pure.mpg.de/cone/journals/resource/954925505259