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  α-Bromo-, α-chloro-, and α-trimethylsilyl-zinc ester enolates. New and universal Reformatsky-type Darzens and Peterson reactions

Fürstner, A. (1987). α-Bromo-, α-chloro-, and α-trimethylsilyl-zinc ester enolates. New and universal Reformatsky-type Darzens and Peterson reactions. Journal of Organometallic Chemistry, 336(3), C33-C36. doi:10.1016/0022-328X(87)85208-7.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0010-18D8-4 Version Permalink: https://hdl.handle.net/21.11116/0000-0008-56CB-3
Genre: Journal Article

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 Creators:
Fürstner, Alois1, Author           
Affiliations:
1Institute of Organic Chemistry, Technical University Graz, A-8010 Graz, Austria, ou_persistent22              

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 Abstract: Low temperature reactions of ethyl dihaloacetates with carbonyl compounds in
the presence of zinc/silver-graphite give α-halo-β-hydroxyalkanoates, which are
readily converted into glycidates by base. Under the same conditions ethyl
(bromo)(trimethylsilyl) acetate with aldehydes and ketones forms α,β-unsaturated esters by a Reformatsky-Peterson reaction combination.

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Language(s): eng - English
 Dates: 1987-08-031987-12-15
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0022-328X(87)85208-7
 Degree: -

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Title: Journal of Organometallic Chemistry
  Abbreviation : J. Organomet. Chem.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Amsterdam : Elsevier
Pages: 4 Volume / Issue: 336 (3) Sequence Number: - Start / End Page: C33 - C36 Identifier: ISSN: 0022-328X
CoNE: https://pure.mpg.de/cone/journals/resource/954925622228