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  Intramolecular Redox-Triggered C-H Functionalization

Jurberg, I. D., Peng, B., Wöstefeld, E., Wasserloos, M., & Maulide, N. (2012). Intramolecular Redox-Triggered C-H Functionalization. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(8), 1950-1953. doi:10.1002/anie.201108639.

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 Creators:
Jurberg, Igor Dias1, Author              
Peng, Bo1, Author              
Wöstefeld, Eckhard1, Author              
Wasserloos, Maximilian1, Author              
Maulide, Nuno1, Author              
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1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              

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 Abstract: Sacrifice for the team: A one-pot method achieves remote functionalization at the α-position of an amine moiety through the sacrificial reduction of a neighboring group. The process takes advantage of an intramolecular redox reaction, thereby avoiding the need for any external oxidants. This method was applied to a concise five-step total synthesis of indolizidine 167B.

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Language(s): eng - English
 Dates: 2012-01-192012-01-20
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201108639
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Pages: - Volume / Issue: 51 (8) Sequence Number: - Start / End Page: 1950 - 1953 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720