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  Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation

Audisio, D., Luparia, M., Oliveira, T., Klütt, D., & Maulide, N. (2012). Diastereodivergent De-epimerization in Catalytic Asymmetric Allylic Alkylation. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(29), 7314-7317. doi:10.1002/anie.201202853.

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 Creators:
Audisio, Davide1, Author           
Luparia, Marco1, Author           
Oliveira, Teresa1, Author           
Klütt, Dina2, Author           
Maulide, Nuno1, Author           
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              
2Service Department Schulze (GC, HPLC), Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_persistent22              

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Free keywords: de-epimerization; diastereodivergence; enantioselectivity; palladium; reaction mechanisms
 Abstract: Diastereomers made to order: In an unprecedented ligand-controlled process a racemic mixture of four stereoisomers can be converted with high selectivity into each one of the diastereomers of the product, at will (see scheme). The mechanism of this deracemization of epimers, that is, a de-epimerization, was also studied.

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Language(s): eng - English
 Dates: 2012-06-132012-07-16
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201202853
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 51 (29) Sequence Number: - Start / End Page: 7314 - 7317 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720