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  Dual Nucleophilic/Electrophilic Capture of In Situ Generated Iminium Ethers: Towards the Synthesis of Functionalized Amide Building Blocks

Peng, B., O'Donovan, D. H., Jurberg, I. D., & Maulide, N. (2012). Dual Nucleophilic/Electrophilic Capture of In Situ Generated Iminium Ethers: Towards the Synthesis of Functionalized Amide Building Blocks. Chemistry-a European Journal, 18(51), 16292-16296. doi:10.1002/chem.201203293.

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 Creators:
Peng, Bo1, Author           
O'Donovan, Daniel H.1, Author           
Jurberg, Igor Dias1, Author           
Maulide, Nuno1, Author           
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              

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 Abstract: The transformation of simple linear amides into a diverse range of branched, functionalized products by conversion to iminium esters is followed by sequential treatment with nucleophiles and electrophiles (see scheme). The method takes advantage of a novel Claisen rearrangement and the use of aromatic substrates greatly facilitates the formation of the intermediate iminium ether.

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Language(s): eng - English
 Dates: 2012-11-142012-12-14
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/chem.201203293
 Degree: -

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Title: Chemistry-a European Journal
  Other : Chem.-Eur. J.
Source Genre: Journal
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Pages: - Volume / Issue: 18 (51) Sequence Number: - Start / End Page: 16292 - 16296 Identifier: ISSN: 0947-6539
CoNE: https://pure.mpg.de/cone/journals/resource/954926979058