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  Asymmetric Counteranion-Directed Catalysis (ACDC): A Remarkably General Approach to Enantioselective Synthesis

Mahlau, M., & List, B. (2012). Asymmetric Counteranion-Directed Catalysis (ACDC): A Remarkably General Approach to Enantioselective Synthesis. Israel Journal of Chemistry, 52(7), 630-638. doi:10.1002/ijch.201200001.

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 Creators:
Mahlau, Manuel1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445585              

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Free keywords: Asymmetric catalysis; cationic intermediates; chirality; enantioselectivity; organocatalysis
 Abstract: Asymmetric counteranion-directed catalysis (ACDC) is a powerful new concept, which can potentially be used to achieve enantioselectivity in any type of reaction proceeding through positively charged intermediates. It has already been applied in different areas of catalysis, such as organocatalysis, transition-metal catalysis, and Lewis acid catalysis. Due to its complementarity with traditional approaches to achieve enantioselection, ACDC holds special promise for long-standing challenges from all areas of catalysis, where matched cases can be designed. ACDC also represents a new way of thinking during method development, which could be of help to chemists from a variety of research areas.

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Language(s): eng - English
 Dates: 2012-01-032012-03-132012-07-122012-07-12
 Publication Status: Published in print
 Pages: 9
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ijch.201200001
 Degree: -

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Title: Israel Journal of Chemistry
  Other : Isr. J. Chem.
Source Genre: Journal
 Creator(s):
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: 52 (7) Sequence Number: - Start / End Page: 630 - 638 Identifier: ISSN: 0021-2148
CoNE: https://pure.mpg.de/cone/journals/resource/954925408770