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  Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films

Boscoboinik, A., Yu, X., Yang, B., Fischer, F. D., Włodarczyk, R., Sierka, M., et al. (2012). Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 51(24), 6005-6008. doi:10.1002/anie.201201319.

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 Creators:
Boscoboinik, Anibal1, Author           
Yu, Xin1, Author           
Yang, Bing1, Author           
Fischer, Frank Daniel2, Author
Włodarczyk, Radosław2, Author
Sierka, Marek3, Author
Shaikhutdinov, Shamil Kamilovich1, Author           
Sauer, Joachim2, Author
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              
2Humboldt-Universität zu Berlin, Department of Chemistry, Unter den Linden 6, 10009 Berlin (Germany), ou_persistent22              
3Friedrich Schiller Universität Jena Institute of Materials Science and Technology, Löbdergraben 32, 07743 Jena (Germany), ou_persistent22              

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Free keywords: density functional calculations; IR spectroscopy; surface structures; thin films; zeolites
 Abstract: Flat pore models: Thin, well-defined aluminosilicate films with tetrahedral [SiO4/2] and [AlO4/2⁻] building blocks that are weakly bound to an underlying metal support contain highly acidic bridging OH species, which exhibit H–D exchange (see picture; Si yellow, O red, Al gray, C black, H white). These films are a model system for surface-science studies of the inner walls of zeolite pores.

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Language(s): eng - English
 Dates: 2012-02-162012-04-262012-06-11
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201201319
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Publ. Info: Weinheim/Bergstr. : Verlag Chemie
Pages: - Volume / Issue: 51 (24) Sequence Number: - Start / End Page: 6005 - 6008 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720