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  Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation

Liao, S., & List, B. (2012). Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation. Advanced Synthesis & Catalysis, 354(13), 2363-2367. doi:10.1002/adsc.201200251.

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 Creators:
Liao, Saihu1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445585              

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Free keywords: asymmetric sulfoxidation; chiral counteranions; iron catalysis; salen ligands; sulfides
 Abstract: A highly active and enantioselective ion-pair sulfoxidation catalyst, consisting of an achiral iron(III)-salen cation and a chiral phosphate counteranion, mediates the oxidization of various sulfides with high yields and enantioselectivities. The enantioselectivities observed, especially for electron-poor substrates, represent the best results so far in manganese and iron-salen systems. This work represents the first application of our concept of asymmetric counteranion-directed catalysis (ACDC) to iron catalysis

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Language(s): eng - English
 Dates: 2012-03-262012-08-222012-09-17
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/adsc.201200251
 Degree: -

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Title: Advanced Synthesis & Catalysis
  Abbreviation : Adv. Synth. Catal.
Source Genre: Journal
 Creator(s):
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Publ. Info: Weinheim, Fed. Rep. of Germany : Wiley-VCH Verlag GmbH
Pages: - Volume / Issue: 354 (13) Sequence Number: - Start / End Page: 2363 - 2367 Identifier: ISSN: 1615-4150
CoNE: https://pure.mpg.de/cone/journals/resource/958634688013