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  Highly Enantioselective Hetero-Diels–Alder Reaction of 1,3-Bis-(silyloxy)-1,3-dienes with Aldehydes Catalyzed by Chiral Disulfonimide

Guin, J., Rabalakos, C., & List, B. (2012). Highly Enantioselective Hetero-Diels–Alder Reaction of 1,3-Bis-(silyloxy)-1,3-dienes with Aldehydes Catalyzed by Chiral Disulfonimide. Angewandte Chemie International Edition, 51(35), 8859-8863. doi:10.1002/anie.201204262.

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 Creators:
Guin, Joyram1, Author              
Rabalakos, Constantinos1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445585              

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Free keywords: asymmetric catalysis; cycloaddition; disulfonimide; heterocycles; organocatalysis
 Abstract: Bulking up with F: The title reaction proceeds using 1 mol % of the new perfluoroisopropyl chiral disulfonimide catalyst 1 to deliver several 2,6-disubstituted and 2,5,6-trisubstituted dihydropyrones in good yields and with excellent enantiomeric ratios. The utility of this methodology is illustrated with the first enantioselective synthesis of a potent aromatase inhibitor.

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Language(s): eng - English
 Dates: 2012-06-012012-06-012012-07-292012-08-27
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201204262
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 51 (35) Sequence Number: - Start / End Page: 8859 - 8863 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851