English
 
User Manual Privacy Policy Disclaimer Contact us
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Measurement of long range H,C couplings in natural products in orienting media: a tool for structure elucidation of natural products.

Verdier, L., Sakhaii, P., Zweckstetter, M., & Griesinger, C. (2003). Measurement of long range H,C couplings in natural products in orienting media: a tool for structure elucidation of natural products. Journal of Magnetic Resonance, 163(2), 353-359. doi:10.1016/S1090-7807(03)00063-6.

Item is

Basic

show hide
Item Permalink: http://hdl.handle.net/11858/00-001M-0000-000E-7090-E Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0028-F08E-9
Genre: Journal Article

Files

show Files
hide Files
:
1587322.pdf (Publisher version), 258KB
Name:
1587322.pdf
Description:
-
Visibility:
Public
MIME-Type / Checksum:
application/pdf / [MD5]
Technical Metadata:
Copyright Date:
-
Copyright Info:
-
License:
-

Creators

show
hide
 Creators:
Verdier, L., Author
Sakhaii, P., Author
Zweckstetter, M.1, Author              
Griesinger, C.2, Author              
Affiliations:
1Research Group of Protein Structure Determination using NMR, MPI for biophysical chemistry, Max Planck Society, ou_578571              
2Department of NMR Based Structural Biology, MPI for biophysical chemistry, Max Planck Society, ou_578567              

Content

show
hide
Free keywords: -
 Abstract: In this paper we show that water insoluble compounds dissolved in poly-γ-benzyl-glutamate are amenable to the measurement of a number of homo- and heteronuclear dipolar couplings. The sensitivity and experimental precision of dipolar couplings are sufficient to obtain a good match with the structure. In order to achieve the necessary precision for H,C dipolar couplings between protons and carbons that are not directly bound a new method for the measurement of heteronuclear long range couplings is introduced that allows a one-parameter fit to a HSQC-based experiment as reference experiment. The methodology is applied to menthol (1R, 3S, 4R).

Details

show
hide
Language(s): eng - English
 Dates: 2003-08
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: DOI: 10.1016/S1090-7807(03)00063-6
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Journal of Magnetic Resonance
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 163 (2) Sequence Number: - Start / End Page: 353 - 359 Identifier: -