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  A Functional-Group-Tolerant Catalytic trans Hydrogenation of Alkynes

Radkowski, K., Sundararaju, B., & Fürstner, A. (2013). A Functional-Group-Tolerant Catalytic trans Hydrogenation of Alkynes. Angewandte Chemie International Edition, 52(1), 355-360. doi:10.1002/anie.201205946.

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 Creators:
Radkowski, Karin1, Author              
Sundararaju, Basker1, Author              
Fürstner, Alois1, Author              
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              

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Free keywords: alkenes; alkynes hydrogenation ruthenium trans reduction
 Abstract: Against the rules: During the hundred years following Sabatier's groundbreaking work on catalytic hydrogenation, syn delivery of the H atoms to the π system of a substrate remained the governing stereochemical rule. An exception has now be found with the use of cationic [Cp*Ru] templates, which accounts for the first practical, functional-group-tolerant, broadly applicable and highly E-selective semihydrogenation method for alkynes (see scheme).

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Language(s): eng - English
 Dates: 2012-09-102013-01-02
 Publication Status: Published in print
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201205946
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag
Pages: 6 Volume / Issue: 52 (1) Sequence Number: - Start / End Page: 355 - 360 Identifier: ISSN: 1521-3773
CoNE: https://pure.mpg.de/cone/journals/resource/0570-0833