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  Pyracenebis(imidazolylidene): A New Janus-Type Biscarbene and Its Coordination to Rhodium and Iridium

Prades, A., Peris, E., & Alcarazo, M. (2012). Pyracenebis(imidazolylidene): A New Janus-Type Biscarbene and Its Coordination to Rhodium and Iridium. Organometallics, 31(12), 4623-4626. doi:10.1021/om3003834.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-7811-1 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-7812-0
Genre: Journal Article

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 Creators:
Prades, Amparo1, Author
Peris, Eduardo1, Author
Alcarazo, M.2, Author           
Affiliations:
1Departamento de Quı́mica Inorgánica y Orgánica, Universitat Jaume I, Avenida Vicente Sos Baynat s/n, Castellón E-12071, Spain, ou_persistent22              
2Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              

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 Abstract: A pyracene-linked bis-azolium compound has been obtained from the bis-annulation of tetrakis(iminopyracene) (TIP) with chloromethyl methyl ether. The resulting bis-azolium salt was readily coordinated to rhodium and iridium, affording bis-NHC complexes with 2-fold symmetry. The X-ray structural characterization of the Rh complex containing the pyracenebis(imidazolylidene) ligand is also reported. The new bis-NHC ligand consists of two linearly opposed (Janus-type) imidazolylidenes annulated to both sides of a pyracene skeleton.

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Language(s): eng - English
 Dates: 2012-06-122012-06-25
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/om3003834
 Degree: -

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Title: Organometallics
  Other : Organometallics
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: 4 Volume / Issue: 31 (12) Sequence Number: - Start / End Page: 4623 - 4626 Identifier: ISSN: 0276-7333
CoNE: https://pure.mpg.de/cone/journals/resource/954925505259
DOI: 10.1021/om3003834