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  Conversion of a singlet silylene to a stable biradical.

Mondal, K. C., Roesky, H. W., Schwarzer, M. C., Frenking, G., Tkach, I., Wolf, H., et al. (2013). Conversion of a singlet silylene to a stable biradical. Angewandte Chemie International Edition, 52(6), 1801-1805. doi:10.1002/anie.201204487.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-000E-802F-B Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0027-C85B-D
Genre: Journal Article

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1629157.pdf (Publisher version), 484KB
 
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 Creators:
Mondal, K. C., Author
Roesky, H. W., Author
Schwarzer, M. C., Author
Frenking, G., Author
Tkach, I.1, Author              
Wolf, H., Author
Kratzert, D., Author
Herbst-Irmer, R., Author
Niepçtter, B., Author
Stalke, D., Author
Affiliations:
1Research Group of Electron Paramagnetic Resonance, MPI for biophysical chemistry, Max Planck Society, ou_578606              

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 Abstract: Silicon becomes colored: Stable biradicals were prepared from an N-heterocyclic carbene stabilized SiCl2 and a cyclic alkyl(amino)carbene, and characterized as two polymorphs. The deep-blue crystals of one polymorph are stable upon exposure to air for about a week, while the solution in THF decomposes rapidly when exposed to air. In a side reaction, the different carbene species react with each other under C[BOND]H activation and C[BOND]C bond formation in the presence of the biradical.

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Language(s): eng - English
 Dates: 2012-12-202013-02-04
 Publication Status: Published in print
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 Rev. Method: Peer
 Identifiers: DOI: 10.1002/anie.201204487
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Title: Angewandte Chemie International Edition
Source Genre: Journal
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Pages: - Volume / Issue: 52 (6) Sequence Number: - Start / End Page: 1801 - 1805 Identifier: ISSN: 0570-0833