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  A laser extraction/combustion technique for in situ δ 13C analysis of organic and inorganic materials

Wieser, M. E., & Brand, W. A. (1999). A laser extraction/combustion technique for in situ δ 13C analysis of organic and inorganic materials. Rapid Communications in Mass Spectrometry, 13(13), 1218-1225.

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BGC0196.pdf (Publisher version), 142KB
 
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 Creators:
Wieser, M. E., Author
Brand, W. A.1, Author           
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1Service Facility Stable Isotope/Gas Analytics, Dr. W. A. Brand, Max Planck Institute for Biogeochemistry, Max Planck Society, ou_1497772              

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Free keywords: Mass-spectrometry Isotope Irms
 Abstract: A CO2 laser extraction system is described for in situ delta(13)C analysis of organic and inorganic materials. Carbonaceous compounds volatilized by the laser are quantitatively converted to CO2 gas by a combustion furnace mounted after the sample chamber. Gases produced by the laser and combustion processes are swept by helium carrier gas and separated by a packed gas chromatography column prior to their introduction to an isotope ratio monitoring mass spectrometer. A sample of lentil bean was analyzed at a spatial resolution of 200 mu m and yielded delta(13)C values with precision of +/-0.3 parts per thousand. The accuracy of delta(13)C measurements was better than +/-0.5 parts per thousand from NBS 22 (mineral oil), USGS 24 (graphite), and IAEA CO-1 (calcium carbonate). Copyright (C) 1999 John Wiley & Sons, Ltd. [References: 9]

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 Dates: 1999
 Publication Status: Issued
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 Identifiers: Other: BGC0196
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Title: Rapid Communications in Mass Spectrometry
Source Genre: Journal
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Publ. Info: New York, NY : John Wiley & Sons
Pages: - Volume / Issue: 13 (13) Sequence Number: - Start / End Page: 1218 - 1225 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/954925574961
ISSN: 0951-4198