English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
  Diastereodivergent Processes in Palladium-Catalyzed Allylic Alkylation

Oliveira, T., Audisio, D., Niyomchon, S., & Maulide, N. (2013). Diastereodivergent Processes in Palladium-Catalyzed Allylic Alkylation. ChemCatChem: heterogeneous & homogeneous & bio-catalysis, 5(6), 1239-1247. doi:10.1002/cctc.201200644.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Oliveira, Teresa1, Author              
Audisio, Davide1, Author              
Niyomchon, Supaporn1, Author              
Maulide, Nuno1, Author              
Affiliations:
1Research Group Maulide, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445614              

Content

show
hide
Free keywords: asymmetric catalysis; alkylation; deracemization; diastereodivergence; pi-allyl isomerization; reaction mechanisms
 Abstract: Dynamic deracemizations are robust strategies wherein a racemate is converted into a single enantiopure product in 100 % yield. A process can be defined as diastereodivergent if multiple diastereomers of the product are possible and if a specific process offers the ability to generate each and every one of them by fine-tuning the reaction conditions. Palladium-catalyzed asymmetric allylic alkylation with stabilized nucleophiles is a versatile strategy that can be used to achieve this goal. In this concept, we summarize the advances that have been made in this field. We also introduce and develop the novel concepts of diastereodivergent deracemization and diastereodivergent de-epimerization.

Details

show
hide
Language(s):
 Dates: 2013-02-21
 Publication Status: Published online
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/cctc.201200644
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: ChemCatChem : heterogeneous & homogeneous & bio-catalysis
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 5 (6) Sequence Number: - Start / End Page: 1239 - 1247 Identifier: Other: 1867-3880
CoNE: https://pure.mpg.de/cone/journals/resource/1867-3880