Teaching an old dog new tricks: Using the flowing afterglow to measure kinetics 
of electron attachment to radicals, ion–ion mutual neutralization, and electron 
catalyzed mutual neutralization.

Shuman, N. S.; Miller, T. M.; Viggiano, A. A.; Troe, J.

doi:10.1016/B978-0-12-396482-3.00005-3

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Teaching an old dog new tricks: Using the flowing afterglow to measure kinetics of electron attachment to radicals, ion–ion mutual neutralization, and electron catalyzed mutual neutralization.

Shuman, N. S., Miller, T. M., Viggiano, A. A., & Troe, J. (2012). Teaching an old dog new tricks: Using the flowing afterglow to measure kinetics of electron attachment to radicals, ion–ion mutual neutralization, and electron catalyzed mutual neutralization. In Advances in atomic, molecular and optical physics (pp. 209-294). Amsterdam: Elsevier.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-000E-EDB4-3 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-C797-D

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Creators:
Shuman, N. S., Author
Miller, T. M., Author
Viggiano, A. A., Author
Troe, J.¹, Author

Affiliations:
1Emeritus Group of Spectroscopy and Photochemical Kinetics, MPI for Biophysical Chemistry, Max Planck Society, ou_578625

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Abstract: Flowing tube apparatuses have been used to study a variety of electron and ion processes at thermal energies. We describe a new technique, variable electron and neutral density attachment mass spectrometry (VENDAMS), which has enabled measurement of rate coefficients for electron attachment to unstable radical molecules and other transient species and for mutual neutralization reactions of anions with noble gas cations, along with, in favorable cases, determination of neutral products of mutual neutralization. Additionally, the method has yielded evidence of a new ternary reaction in which an electron third body enhances anion–cation neutralization at high plasma densities.

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Language(s): eng - English

Dates: Date issued: 2012

Publication Status: Issued

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Rev. Type: Peer

Identifiers: DOI: 10.1016/B978-0-12-396482-3.00005-3

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Title: Advances in atomic, molecular and optical physics

Source Genre: Series

Creator(s):
Berman, R. E., Author
Arimondo, E., Author
Lin, C. C., Author

Affiliations:
-

Publ. Info: Amsterdam : Elsevier

Pages: - Volume / Issue: 61 Sequence Number: - Start / End Page: 209 - 294 Identifier: ISBN: 978-0-12-396482-3