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  Synthesis, Crystal Structures, and Hydrogen-Storage Properties of Eu(AlH4)(2) and Sr(AlH4)(2) and of Their Decomposition Intermediates, EuAlH5 and SrAlH5

Pommerin, A., Wosylus, A., Felderhoff, M., Schüth, F., & Weidenthaler, C. (2012). Synthesis, Crystal Structures, and Hydrogen-Storage Properties of Eu(AlH4)(2) and Sr(AlH4)(2) and of Their Decomposition Intermediates, EuAlH5 and SrAlH5. Inorganic Chemistry, 51(7), 4143-4150. doi:10.1021/ic202492v.

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 Creators:
Pommerin, André1, Author           
Wosylus, Aron1, Author           
Felderhoff, Michael1, Author           
Schüth, Ferdi1, Author           
Weidenthaler, Claudia1, Author           
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1Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, DE, ou_1445589              

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 Abstract: Complex Eu(AlH4)(2) and SrAlH4(2) hydrides have been prepared by a mechanochemical metathesis reaction from NaAlH4 and europium or strontium chlorides. The crystal structures were solved from powder X-ray diffraction data in combination with solid-state 27Al NMR spectroscopy. The thermolysis pathway was analyzed in detail, allowing identification of new intermediate EuAlH5/SrAlH5 compounds. Rehydrogenation experiments indicate that the second decomposition step is reversible.

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Language(s): eng - English
 Dates: 2011-11-202012-03-092012-04-02
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ic202492v
 Degree: -

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Title: Inorganic Chemistry
  Abbreviation : Inorg. Chem.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 51 (7) Sequence Number: - Start / End Page: 4143 - 4150 Identifier: ISSN: 0020-1669
CoNE: https://pure.mpg.de/cone/journals/resource/0020-1669