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  Chiral Task-Specific Solvents for Mandelic Acid and Their Impact on Solution Thermodynamics and Crystallization Kinetics

Tulashie, S. K., von Langermann, J., Lorenz, H., & Seidel-Morgenstern, A. (2011). Chiral Task-Specific Solvents for Mandelic Acid and Their Impact on Solution Thermodynamics and Crystallization Kinetics. Crystal Growth & Design, 11(1), 240-246. doi:10.1021/cg101179y.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0013-8CD9-0 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-B40E-C
Genre: Journal Article

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 Creators:
Tulashie, S. K.1, 2, Author              
von Langermann, J.1, Author              
Lorenz, H.1, Author              
Seidel-Morgenstern, A.1, 2, Author              
Affiliations:
1Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738150              
2Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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 Abstract: The synthesis and application of enantiopure short-chain mandelic acid esters as chiral task-specific solvents were investigated for the determination of hetereochiral interactions between chiral solutes and chiral solvents. Because of specific chiral interactions between the mandelic acid enantiomers as solutes and the S-configured solvents for this chiral system, asymmetric behavior was elucidated. Differences for (R)- and (S)-mandelic acid were determined with respect to solution thermodynamics and crystallization kinetics for the chiral solvents (S)-mandelic acid n-propyl ester [(S)-n-propyl mandelate] and (S)-mandelic acid isopropyl ester [(S)-isopropyl mandelate]. These differences were explained via evaluation of enantiospecific interactions applying molecular modeling methods. copyright American Chemical Society [accessed November 19th, 2010]

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Language(s): eng - English
 Dates: 2011
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: eDoc: 516731
DOI: 10.1021/cg101179y
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Title: Crystal Growth & Design
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 11 (1) Sequence Number: - Start / End Page: 240 - 246 Identifier: ISSN: 1528-7483
CoNE: /journals/resource/110978984570353