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  Solubility and Metastable Zone Width of the Methionine Enantiomers and Their Mixtures in Water

Polenske, D., & Lorenz, H. (2009). Solubility and Metastable Zone Width of the Methionine Enantiomers and Their Mixtures in Water. Journal of Chemical and Engineering Data, 54(8), 2277-2280. doi:10.1021/je9001834.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0013-93B5-5 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-B56C-A
Genre: Journal Article

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 Creators:
Polenske, D.1, Author              
Lorenz, H.1, Author              
Affiliations:
1Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738150              

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 Abstract: The characterizations of the ternary phase diagram and the metastable zone width are important issues for enantioseparation by crystallization procedures. In this work, a systematic study of the solubility and metastable zone width data of l-methionine, dl-methionine, and different mixtures of the enantiomers in water as solvent was performed. The eutectic composition in the chiral system in the presence of the solvent as an important characteristic for enantioselective crystallization was determined in the temperature range between (1 and 60) °C. A significant shift of this composition was observed. Copyright © 2009 American Chemical Society. [accessed November 24, 2009]

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Language(s): eng - English
 Dates: 2009
 Publication Status: Published in print
 Pages: -
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 Table of Contents: -
 Rev. Method: Peer
 Identifiers: eDoc: 437828
DOI: 10.1021/je9001834
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Title: Journal of Chemical and Engineering Data
Source Genre: Journal
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Publ. Info: Washington : American Chemical Society
Pages: - Volume / Issue: 54 (8) Sequence Number: - Start / End Page: 2277 - 2280 Identifier: ISSN: 0021-9568
CoNE: https://pure.mpg.de/cone/journals/resource/991042728182784