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  VLE and LLE data for the system cyclohexane plus cyclohexene plus water plus cycloblexanol

Steyer, F., & Sundmacher, K. (2004). VLE and LLE data for the system cyclohexane plus cyclohexene plus water plus cycloblexanol. Journal of Chemical and Engineering Data, 49(6), 1675-1681. doi:10.1021/je049902w.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0013-9E3F-8 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0019-86EE-8
Genre: Journal Article

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 Creators:
Steyer, Frank1, Author              
Sundmacher, Kai1, 2, Author              
Affiliations:
1Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738151              
2Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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 Abstract: The ternary system cyclohexene + water + cyclohexanol is currently being studied with the aim of carrying out the reaction of cyclohexene and water to cyclohexanol in a reactive distillation column. The challenge this system poses for such a reactive separator lies in the liquid-liquid phase splitting behavior, which adds a third effect in addition to reaction and distillation. Cyclohexane is added as a fourth component into these studies, representing any C₆ inerts. To be able to describe the activities of all four components, measurements were conducted of the liquid-liquid and vapor-liquid equilibria, and appropriate NRTL parameters matching both vapor-liquid and liquid-liquid phase splitting behavior were identified.

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Language(s): eng - English
 Dates: 2004
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 207626
Other: 40/04
DOI: 10.1021/je049902w
 Degree: -

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Title: Journal of Chemical and Engineering Data
Source Genre: Journal
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Publ. Info: -
Pages: - Volume / Issue: 49 (6) Sequence Number: - Start / End Page: 1675 - 1681 Identifier: -