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  Singular Points of Reactive Distillation Systems

Qi, Z., Flockerzi, D., & Sundmacher, K. (2004). Singular Points of Reactive Distillation Systems. AIChE Journal, 50, 2866-2876. doi:10.1002/aic.10259.

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 Urheber:
Qi, Zhiwen1, Autor           
Flockerzi, D.2, Autor           
Sundmacher, Kai1, 3, Autor           
Affiliations:
1Process Systems Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738151              
2Systems and Control Theory, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738154              
3Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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 Zusammenfassung: For the conceptual design of countercurrently operated reactive distillation columns, fast methods are needed to estimate potential top and bottom products. The possible column bottom product composition can be determined from the stable singular points of a batch reactive reboiler. In a similar manner the top product composition can be obtained from the stable singular points of a batch reactive condenser. Geometrically, the singular points of both batch processes are located on a common potential singular point surface (PSPS) whose trajectory depends on the reaction stoichiometry and the phase equilibria. At the singular points, the PSPS intersects a reaction kinetic surface that is dependent on the reaction rate expression and the phase equilibrium of a reference component. Based on the singularity analysis, a single-feed reactive distillation column can be designed. Several hypothetical and real reaction systems are analyzed to illustrate the singularity analysis and the design procedure. Copyright © 1999–2013 John Wiley & Sons, Inc. All Rights Reserved. [accessed 2013 August 15th]

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Sprache(n): eng - English
 Datum: 2004
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: Expertenbegutachtung
 Identifikatoren: DOI: 10.1002/aic.10259
Anderer: 30/04
 Art des Abschluß: -

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Titel: AIChE Journal
Genre der Quelle: Zeitschrift
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Seiten: - Band / Heft: 50 Artikelnummer: - Start- / Endseite: 2866 - 2876 Identifikator: -