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  Esterification of acetic acid with butanol in the presence of ion-exchange resins as catalysts

Gangadwala, J., Mankar, S., Mahajani, S., Stein, E., & Kienle, A. (2003). Esterification of acetic acid with butanol in the presence of ion-exchange resins as catalysts. Industrial and Engineering Chemistry Research, 42(10), 2146-2155. doi:10.1021/ie0204989.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0013-A001-1 Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0018-6930-B
Genre: Journal Article

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Gangadwala, J.1, Author              
Mankar, S., Author
Mahajani, S., Author
Stein, E.1, Author              
Kienle, A.1, 2, Author              
Affiliations:
1Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738153              
2Otto-von-Guericke-Universität Magdeburg, External Organizations, ou_1738156              

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 Abstract: The esterification of acetic acid with n-butanol was studied in the presence of ion-exchange resin catalysts such as Amberlyst-15 to determine the intrinsic reaction kinetics. The effect of various parameters such as temperature, mole ratio, catalyst loading, and particle size was studied. Kinetic modeling was performed to obtain the parameters related to intrinsic kinetics. Pseudohomogeneous, Eley-Rideal, Langmuir-Hinshelwood-Hougen-Watson (LHHW), and modified LHHW models were developed. The kinetics for the side-reaction etherification was also investigated. The rate expressions would be useful in the simulation studies for reactive distillation. The experimental data generated for the reaction under total reflux were validated successfully using the developed rate equation and estimated values of kinetic parameters. Copyright © 2003 American Chemical Society [accessed 2014 March 28th]

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Language(s): eng - English
 Dates: 2003
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: -
 Identifiers: eDoc: 125064
Other: 23/03
DOI: 10.1021/ie0204989
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Title: Industrial and Engineering Chemistry Research
Source Genre: Journal
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Pages: - Volume / Issue: 42 (10) Sequence Number: - Start / End Page: 2146 - 2155 Identifier: -