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  The Iron (III)-catalyzed oxidation of ethanol by hydrogen peroxide: a thermokinetic oscillator

Zeyer, K.-P., Mangold, M., Obertopp, T., & Gilles, E. D. (1999). The Iron (III)-catalyzed oxidation of ethanol by hydrogen peroxide: a thermokinetic oscillator. Journal of Physical Chemistry, 103A(28), 5515-5522. doi:10.1021/jp990710v.

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Datensatz-Permalink: https://hdl.handle.net/11858/00-001M-0000-0013-A285-7 Versions-Permalink: https://hdl.handle.net/11858/00-001M-0000-0027-AC6A-4
Genre: Zeitschriftenartikel

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 Urheber:
Zeyer, K.-P.1, Autor           
Mangold, M.1, Autor           
Obertopp, T.2, Autor
Gilles, E. D.2, 3, Autor           
Affiliations:
1Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738153              
2Universität Stuttgart, ou_persistent22              
3Systems Biology, Max Planck Institute for Dynamics of Complex Technical Systems, Max Planck Society, ou_1738155              

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 Zusammenfassung: We present an experimental and theoretical study of a laboratory scale continuous flow stirred tank reactor (CSTR) in which the exothermiciron(III)-nitrate catalyzed oxidation of ethanol with hydrogen peroxideto ethanal and acetic acid takes place. This reaction can display temperature and concentration oscillations when it is performed in a CSTR. A model is known in the literature, which is derived from a more detailed mechanism. We investigate the behavior of the system under different conditions using the volumetric flow of the cooling water as an experimental bifurcation parameter. The model is analyzed by one and two parameter continuation of stationary and periodic solutions. We characterize period doubling sequences to chaos, homoclinic orbits, and cross-shaped diagrams, which separate regions of oscillations and bistability. Copyright © 1999 American Chemical Society [accessed 2014 March 31st]

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Sprache(n): eng - English
 Datum: 1999
 Publikationsstatus: Erschienen
 Seiten: -
 Ort, Verlag, Ausgabe: -
 Inhaltsverzeichnis: -
 Art der Begutachtung: -
 Identifikatoren: eDoc: 111971
DOI: 10.1021/jp990710v
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Titel: Journal of Physical Chemistry
Genre der Quelle: Zeitschrift
 Urheber:
Affiliations:
Ort, Verlag, Ausgabe: -
Seiten: - Band / Heft: 103A (28) Artikelnummer: - Start- / Endseite: 5515 - 5522 Identifikator: -