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  Synthesis of Substituted Tetrahydropyrans via Intermolecular Reactions of δ-Halocarbanions with Aldehydes

Barbasiewicz, M., Brud, A., & Makosza, M. (2007). Synthesis of Substituted Tetrahydropyrans via Intermolecular Reactions of δ-Halocarbanions with Aldehydes. Synthesis, 2007(8), 1209-1213. doi:10.1055/s-2007-965972.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0013-CE05-9 Version Permalink: http://hdl.handle.net/21.11116/0000-0003-CC09-E
Genre: Journal Article

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Barbasiewicz, M, Author
Brud, AJ1, Author              
Makosza, M, Author
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1External Organizations, ou_persistent22              

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 Abstract: Intramolecular substitution in δ-halocarbanions leading to cyclobutanes is a relatively slow process, thus they readily add to carbonyl groups; the thus-produced anionic adducts cyclize to tetrahydropyran derivatives. A simple mechanistic discussion, optimization of the reaction conditions, and scope of the reaction is presented.

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 Dates: 2007-04
 Publication Status: Published in print
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 Rev. Method: -
 Identifiers: DOI: 10.1055/s-2007-965972
BibTex Citekey: BarbasiewiczBM2007
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Title: Synthesis
Source Genre: Journal
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 2007 (8) Sequence Number: - Start / End Page: 1209 - 1213 Identifier: ISSN: 0039-7881
CoNE: https://pure.mpg.de/cone/journals/resource/954925448757