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  Fluorescence screening of tartaric acid-derived azamacrocycles synthesized via sequential hydroformylation/reductive amination as potential ligands for asymmetric catalysis

Angelovski, G., Keränen, M., & Eilbracht, P. (2005). Fluorescence screening of tartaric acid-derived azamacrocycles synthesized via sequential hydroformylation/reductive amination as potential ligands for asymmetric catalysis. Tetrahedron: Asymmetry, 16(11), 1919-1926. doi:10.1016/j.tetasy.2005.03.035.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0013-D6A9-9 Version Permalink: https://hdl.handle.net/21.11116/0000-0004-6FB3-6
Genre: Journal Article

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https://www.sciencedirect.com/science/article/pii/S0957416605002922 (Publisher version)
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 Creators:
Angelovski, G1, Author           
Keränen, MD, Author
Eilbracht, P, Author
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1External Organizations, ou_persistent22              

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 Abstract: Azamacrocyclic fluorophores containing piperazine units were synthesized
using sequential rhodium-catalyzed regioselective hyd











Azamacrocycles containing a
tartaric acid-derived unit and aryl units were synthesized via
rhodium-catalyzed hydroformylation and subsequent
reductive amination in a tandem or stepwise fashion.
Upon fluorescence emission experiments, some of the macrocycles
showed chelating affinities towards transition metals such as zinc or rhodium.

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 Dates: 2005-06
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: BibTex Citekey: 3342
DOI: 10.1016/j.tetasy.2005.03.035
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Title: Tetrahedron: Asymmetry
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 16 (11) Sequence Number: - Start / End Page: 1919 - 1926 Identifier: ISSN: 0957-4166
CoNE: https://pure.mpg.de/cone/journals/resource/954925577039