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  Complex dynamical behavior from coupling between a catalyzed Belousov-Zhabotinskii-like reaction and its uncatalyzed oscillatory component in a flow reactor

Dutt, A. K. (2002). Complex dynamical behavior from coupling between a catalyzed Belousov-Zhabotinskii-like reaction and its uncatalyzed oscillatory component in a flow reactor. Journal of Physical Chemistry B, 106(42): 1, pp. 11069-11072.

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Item Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-0DE6-E Version Permalink: http://hdl.handle.net/11858/00-001M-0000-0014-0DE7-C
Genre: Journal Article
Alternative Title : J. Phys. Chem. B

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 Creators:
Dutt, A. K.1, Author
Affiliations:
1Max Planck Institute of Molecular Physiology, Max Planck Society, ou_1753286              

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 Abstract: We have investigated the relationship between the ferroin- catalyzed gallic acid/bromate oscillatory reaction with its uncatalyzed oscillatory component in the light of experimental findings and mechanistic understanding. Low stirring and high temperature increase the oscillation frequency and decrease the amplitude in this catalyzed system, which has been explained in terms of stirring and mixing effects. The uncatalyzed component is reported to exhibit bistability at 20 degreesC (room temperature) in a new concentration region and oscillations and bistability at very low flow rate in the presence of an additional feed of bromide ions.

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Language(s): eng - English
 Dates: 2002-10-24
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Method: Peer
 Identifiers: eDoc: 6074
 Degree: -

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Title: Journal of Physical Chemistry B
  Alternative Title : J. Phys. Chem. B
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 106 (42) Sequence Number: 1 Start / End Page: 11069 - 11072 Identifier: -