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  A Convenient Preparation of Functionalized Arylzinc Compounds by the Reaction of Zinc/Silver-Graphite with Aryl Iodides

Fürstner, A., Singer, R., & Knochel, P. (1994). A Convenient Preparation of Functionalized Arylzinc Compounds by the Reaction of Zinc/Silver-Graphite with Aryl Iodides. Tetrahedron Letters, 35(7), 1047-1050. doi:10.1016/S0040-4039(00)79962-X.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A498-2 Version Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A499-F
Genre: Journal Article

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 Creators:
Fürstner, Alois1, Author           
Singer, Robert2, Author
Knochel, Paul2, Author
Affiliations:
1Research Department Fürstner, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445584              
2Fachbereich Chemie der Philipps-Universität Marburg, Hans-Meewein-Straße, D-35043 Marburg (Germany), ou_persistent22              

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 Abstract: Aryl- and hetero-aryl iodides react under very mild conditions (THF, 25 °C) with a Zn(Ag) couple deposited on graphite leading to the corresponding zinc reagents in excellent yields. In the presence of CuCN·2LiCl or catalytic amounts of Pd(0), these unsaturated zinc species can be acylated, allylated or coupled with iodoalkenes.

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Language(s): eng - English
 Dates: 1993-12-011993-12-152001-03-151994-02-14
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0040-4039(00)79962-X
 Degree: -

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Title: Tetrahedron Letters
  Abbreviation : Tetrahedron Lett.
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: 4 Volume / Issue: 35 (7) Sequence Number: - Start / End Page: 1047 - 1050 Identifier: ISSN: 0040-4039
CoNE: https://pure.mpg.de/cone/journals/resource/954925448772