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  Catalytic Asymmetric Reductive Amination of Aldehydes via Dynamic Kinetic Resolution

Hoffmann, S., Nicoletti, M., & List, B. (2006). Catalytic Asymmetric Reductive Amination of Aldehydes via Dynamic Kinetic Resolution. Journal of the American Chemical Society, 128(40), 13074-13075. doi:10.1021/ja065404r.

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Item Permalink: https://hdl.handle.net/11858/00-001M-0000-0014-A468-E Version Permalink: https://hdl.handle.net/21.11116/0000-0008-40D4-0
Genre: Journal Article

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 Creators:
Hoffmann, Sebastian1, Author           
Nicoletti, Marcello1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445585              

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 Abstract: A novel organocatalytic asymmetric reductive amination of aldehydes has been developed. Treating racemic α-branched aldehydes with p-anisidine and a Hantzsch ester in the presence of our previously developed phosphoric acid catalyst, TRIP, gave β-branched secondary amines in excellent yields and enantioselectivities via an efficient dynamic kinetic resolution. The process is applicable to several different aromatic aldehydes and amines but gives slightly reduced enantiomeric ratios with aliphatic aldehydes.

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Language(s): eng - English
 Dates: 2006-07-272006-09-202006-10-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/ja065404r
 Degree: -

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Title: Journal of the American Chemical Society
  Other : JACS
  Abbreviation : J. Am. Chem. Soc.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: 128 (40) Sequence Number: - Start / End Page: 13074 - 13075 Identifier: ISSN: 0002-7863
CoNE: https://pure.mpg.de/cone/journals/resource/954925376870