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  Catalytic Asymmetric Acylcyanation of Imines

Pan, S. C., Zhou, J., & List, B. (2007). Catalytic Asymmetric Acylcyanation of Imines. Angewandte Chemie International Edition, 46(4), 612-614. doi:10.1002/anie.200603630.

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 Creators:
Pan, Subhas Chandra1, Author              
Zhou, Jian2, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445585              
2Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445589              

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Free keywords: acylcyanation; asymmetric catalysis; organocatalysis; Strecker reaction; thiourea
 Abstract: The less problematic acetyl cyanide can be used instead of toxic HCN for the highly enantioselective acyl‐Strecker‐type reaction. In the presence of an N‐benzylimine and a catalytic amount of Jacobsen's catalyst 1, the desired α‐amidonitrile is obtained in excellent enantioselectivity and yield.

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Language(s): eng - English
 Dates: 2006-09-052007-01-102007-01-15
 Publication Status: Published in print
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.200603630
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 46 (4) Sequence Number: - Start / End Page: 612 - 614 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851