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  CO oxidation on metal-supported ultrathin oxide films: What makes them active?

Martynova, Y., Shaikhutdinov, S. K., & Freund, H.-J. (2013). CO oxidation on metal-supported ultrathin oxide films: What makes them active? ChemPhysChem, 5(8), 2162-2166. doi:10.1002/cctc.201300212.

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manuscript submitted.pdf (Any fulltext), 292KB
 
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2013
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Wiley
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 Creators:
Martynova, Yulia1, Author           
Shaikhutdinov, Shamil K.1, Author           
Freund, Hans-Joachim1, Author           
Affiliations:
1Chemical Physics, Fritz Haber Institute, Max Planck Society, ou_24022              

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Free keywords: carbon monoxide; oxidation; model catalysts; thin films; oxide films
 Abstract: It depends on O: The catalytic properties of ultrathin oxide films are studied by using the low-temperature oxidation of CO as a benchmark reaction. The results reveal a strong correlation between the activity and the desorption energy of the most weakly bound oxygen species present on these films under net oxidizing conditions at near-atmospheric pressures. The results suggest the use of oxygen binding energy as a suitable descriptor for the reaction.

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Language(s): eng - English
 Dates: 2013-03-202013-052013-05-312013-08
 Publication Status: Published in print
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/cctc.201300212
 Degree: -

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Title: ChemPhysChem
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: 5 (8) Sequence Number: - Start / End Page: 2162 - 2166 Identifier: ISSN: 1439-4235
CoNE: https://pure.mpg.de/cone/journals/resource/954925409790