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  Catalytic Asymmetric Three-Component Synthesis of Homoallylic Amines

Gandhi, S., & List, B. (2013). Catalytic Asymmetric Three-Component Synthesis of Homoallylic Amines. Angewandte Chemie International Edition, 52(9), 2573-2576. doi:10.1002/anie.201209776.

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 Creators:
Gandhi, Shikha1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445585              

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Free keywords: asymmetric catalysis; disulfonimides; homoallylic compounds; multicomponent reactions; synthetic methods
 Abstract: It takes three to make things go right: The first direct asymmetric three‐component reaction of aldehydes, carbamates, and allyltrimethylsilane leading to enantioenriched homoallylic amines has been developed using a new chiral disulfonimide catalyst (see scheme). The method employs readily available, inexpensive, and nontoxic starting materials and is applicable to both aromatic and aliphatic aldehydes.

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Language(s): eng - English
 Dates: 2012-12-062013-01-252013-02-25
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201209776
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 52 (9) Sequence Number: - Start / End Page: 2573 - 2576 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851