English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
 
 
DownloadE-Mail
  Disulfonimide-Catalyzed Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions

Ratjen, L., García-García, P., Lay, F., Beck, M. E., & List, B. (2011). Disulfonimide-Catalyzed Asymmetric Vinylogous and Bisvinylogous Mukaiyama Aldol Reactions. Angewandte Chemie International Edition, 50(3), 754-758. doi:10.1002/anie.201005954.

Item is

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Ratjen, Lars1, Author           
García-García, Pilar1, Author           
Lay, Frank1, Author           
Beck, Michael Edmund2, Author
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, ou_1445585              
2Bayer CropScience AG, Alfred-Nobel-Strasse 50, 40789 Monheim am Rhein (Germany), ou_persistent22              

Content

show
hide
Free keywords: aldol reactions; organocatalysis; regioselectivity; synthetic methods; vinylogy
 Abstract: Let's talk about six! A new chiral disulfonimide catalyzed vinylogous Mukaiyama aldol addition of crotonic acid derived nucleophiles to aldehydes has been developed and the concept of vinylogy was further expanded to double vinylogous, sorbic acid derived nucleophiles. This reaction is an example of a previously unknown ε‐selective bisvinylogous Mukaiyama Aldol addition that extends the substrate by six carbon atoms (see scheme).

Details

show
hide
Language(s): eng - English
 Dates: 2010-09-222010-12-172011-01-17
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201005954
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 50 (3) Sequence Number: - Start / End Page: 754 - 758 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851