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  Stabilization of a Two-Coordinate [GeCl]+ Cation by Simultaneous σ and π Donation from a Monodentate Carbodiphosphorane

Khan, S., Gopakumar, G., Thiel, W., & Alcarazo, M. (2013). Stabilization of a Two-Coordinate [GeCl]+ Cation by Simultaneous σ and π Donation from a Monodentate Carbodiphosphorane. Angewandte Chemie International Edition: a journal of the Gesellschaft Deutscher Chemiker, 52(21), 5644-5647. doi:10.1002/anie.201300677.

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anie_201300677_sm_miscellaneous_information.pdf (Supplementary material), 3MB
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anie_201300677_sm_miscellaneous_information.pdf
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Supporting information
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Public
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application/pdf / [MD5]
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Copyright Date:
2013
Copyright Info:
Wiley-VCH 69451 Weinheim, Germany
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 Creators:
Khan, Shabana1, Author              
Gopakumar, Gopinadhanpillai2, Author              
Thiel, Walter2, Author              
Alcarazo, Manuel1, Author              
Affiliations:
1Research Group Alcarazo, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445592              
2Research Department Thiel, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445590              

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Free keywords: carbodiphosphoranes; density functional calculations; electronic structure; germanium; tin
 Abstract: Give me four: The synthesis, structure, and reactivity of [GeCl]+ and [SnCl]+ cations bearing a carbodiphosphorane as ancillary ligand are presented. In the Ge compound, simultaneous σ and π donation from the carbodiphosphorane to Ge is observed (see HOMO (left) and HOMO−1 (right); C black, H white, P orange, Cl green, Ge purple (not visible)), whereas only the σ dative component is present in the Sn analogue.

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Language(s): eng - English
 Dates: 2013-01-252013-04-122013-05-17
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.201300677
 Degree: -

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Title: Angewandte Chemie International Edition : a journal of the Gesellschaft Deutscher Chemiker
Source Genre: Journal
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Publ. Info: Weinheim/Bergstr. : Verlag Chemie
Pages: 4 Volume / Issue: 52 (21) Sequence Number: - Start / End Page: 5644 - 5647 Identifier: ISSN: 0570-0833
CoNE: https://pure.mpg.de/cone/journals/resource/110984073528720